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Pavithra PS, Mehta A, Verma RS

These enzymes convert superoxide (O 2 - ) into hydrogen peroxide (H 2 O 2 ), which acts as a secondary messenger in redox-sensitive signaling pathways such as NF-B, MAPK, and HIF-1 (Yang et al., 2026

The two human 3-hydroxysteroid dehydrogenases have been investigated in detail by Thomas and coworkers (e.g., Thomas et al., 2005), and their studies indicate that the 3-ketosteroid 5-AD formed by oxidation of dehydroepiandrosterone with NAD + as a coenzyme remains as an intermediate bound to the enzyme prior to its isomerization to 4-AD